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・ Piperhill
・ Piperi
・ Piperi (Greece)
・ Piperi (tribe)
・ Piperia
・ Piperia candida
・ Piperia colemanii
・ Piperia cooperi
・ Piperia elegans
・ Piperia elongata
・ Piperia leptopetala
・ Piperia michaelii
・ Piperia transversa
・ Piperia unalascensis
・ Piperia yadonii
Piperic acid
・ Piperidine
・ Piperidine N-piperoyltransferase
・ Piperidinedione
・ Piperidinone
・ Piperidione
・ Piperidolate
・ Piperidylthiambutene
・ Piperine
・ Piperitone
・ Piperitsa
・ Piperkov Chiflik
・ Piperlime
・ Piperlongumine
・ Piperlonguminine


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Piperic acid : ウィキペディア英語版
Piperic acid

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Piperic acid is a chemical often obtained by the base-hydrolysis of the alkaloid piperine from black pepper,〔http://chestofbooks.com/health/aromatherapy/The-Volatile-Oils-Vol1/Heliotropin.html〕 followed by acidification of the corresponding salt.〔http://www.erowid.org/archive/rhodium/chemistry/3base/piperonal.pepper/degradation.piperine/index.html〕 Piperic acid is an intermediate in the synthesis of other compounds such as piperonal, and as-such may be used to produce fragrances, perfumes flavorants and drugs as well as other useful compounds.
==Preparation==
Piperic acid can be prepared from the commercially-available alkaloid piperine, a cyclic amide containing a piperidine group, by reacting it with a hydroxide such as potassium hydroxide, then acidifying the formed piperate salt with hydrochloric acid or another acid. The toxic compound piperidine is given off during the base-hydrolysis of piperine and as-such, safety precautions should be taken.
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